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Omission of the comproportionation kinetics by selecting the triad model also reduces the number of parameters that require estimating, reducing uncertainty in the overall parameter space

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When the complex does ionize intact, the copper isotope pattern is a decisive confirmation: the two stable isotopes occur at roughly sixty-nine and thirty-one percent natural abundance, giving a distinctive doublet two mass units apart at approximately a two-to-one intensity ratio that is nothing like the isotope envelope of a small peptide

That is not a great combination